3D Laser Micro‐ and Nanoprinting: Challenges for Chemistry

3D printing is a powerful emerging technology for the tailored fabrication of advanced functional materials. This Review summarizes the state‐of‐the art with regard to 3D laser micro‐ and nanoprinting and explores the chemical challenges limiting its full exploitation: from the development of advanced functional materials for applications in cell biology and electronics to the chemical barriers that need to be overcome to enable fast writing velocities with resolution below the diffraction limit. We further explore chemical means to enable direct laser writing of multiple materials in one resist by highly wavelength selective (λ‐orthogonal) photochemical processes. Finally, chemical processes to construct adaptive 3D written structures that are able to respond to external stimuli, such as light, heat, pH value, or specific molecules, are highlighted, and advanced concepts for degradable scaffolds are explored.     

Diameter of a direct power of a finite group

We present two conjectures concerning the diameter of a direct power of a finite group. The first conjecture states that the diameter of Gⁿ with respect to each generating set is at most n(|G|?rank(G)); and the second one states that there exists a generating set 𝒜, of minimum size, for Gⁿ such that the diameter of Gⁿ with respect to 𝒜 is at most n(|G|?rank(G)). We will establish evidence for each of the above mentioned conjectures.     

基于电磁振动上料的茶梗和昆虫异物近红外光谱和荧光图像在线检测研究

茶叶是大众青睐的健康饮品之一,但茶叶在机器采收和加工过程中,容易混入茶梗和昆虫异物,污染茶叶、影响其质量安全,是未来应防范和检测的重点。X射线成像技术,根据食品基质和异物的密度差实施检测,广泛适用于金属异物并延伸至高密度塑料,但对于茶梗、昆虫这类低密度有机异物尚不适用,所以迫切需要研发新型无损检测技术和方法。针对片状茶叶重叠、遮掩异物的问题,提出了电磁振动上料辅助近红外光谱和荧光图像的检测方案,进行绿茶中的内源性异物茶梗和外源性异物昆虫的在线检测研究。通过电磁振动上料辅助近红外光谱和荧光成像系统,采集了600～1 050 nm范围的近红外光谱600条和RGB-N四通道图像各65幅。采用451条光谱进行建模,其余149条光谱作为预测集,评估模型的性能,比较了去趋势(Detrending)、多元散射校正(MSC)、标准正态变换(SNV)、变权重正态变换(VSN)、迭代自适应加权惩罚最小二乘法(airPLS)、不对称最小二乘法(ALS)、光程估计与校正(OPLEC)等不同光谱预处理方法的处理效果,其中OPLEC能较好地消除散射效应,偏最小二乘判别分析(PLS-DA)模型的正确识别率由78%提...     

大型结构分析程序系统单元库更新

阐述了大型结构分析程序系统单元库更新的概念及其意义，报告了装入ＡＰ－１程序系统单元库的精化四节点及八节点平面等参元的情况，给出了更新前、后单元通过考题库测试的结果及与其它程序系统结果的比较。数值结果表明通过更新单元来提高程序系统的分析精度与计算效率从而增强其竞争力是可行的。     

PVDF应力测量技术及在混凝土冲击实验中的应用

介绍了使用PVDF(polyvinylidene fluoride,聚偏二氟乙烯)应力计的应力直接测量技术。在SHPB装置上进行自制PVDF应力计动态压电系数的标定实验,分析了应力集中、横向泊松效应、摩擦效应对PVDF应力计信号及动态压电系数的影响。用PVDF应力计进行了混凝土的冲击压缩实验。利用混凝土前后端面PVDF应力计信号分析了实验过程中混凝土试样的应力均匀性。与应变计直测应变技术相结合得到了混凝土的动态应力-应变关系。     

周边嵌入弹性圆薄板非线性自由振动直接摄动解法

采用弹性圆薄板中心无量纲振幅和板厚与半径的比值为参数。将挠度、应力函数对半径的导数以及自由振动频率展开为双参数的幂级数。用直接摄动法获得各级递推线性偏微分方程。应用变分法求得各级递推方程的近似解，从而给出弹性圆薄板非线性自由振动频率的基本公式。     

Direct Numerical Simulation of Statistically Stationary One- and Two-Phase Turbulent Combustion: A Turbulent Injection Procedure

A new turbulent injection procedure dedicated to fully compressible direct numerical simulation (DNS) or large eddy simulation (LES) solvers is proposed. To avoid the appearance of spurious acoustic waves, this method is based on an accurate tracking of the turbulent structures crossing the boundary at the inlet of the domain. A finite difference DNS solver has been coupled with a spectral simulation in which a statistically stationary homogeneous turbulence evolves to provide fluctuating boundary conditions.A new turbulence forcing method, dedicated to spectral solvers, has been developed as well to control the major properties of the injected flow (turbulent kinetic energy, dissipation rate and integral length scale). One-dimensional Navier–Stokes characteristic boundary conditions extended to non-stationary flows are coupled with the injection procedure to evaluate is potential in four various configurations: spatially decaying turbulence, dispersion of vaporizing sprays, propagation of one- and two-phase V-shape turbulent flames.     

Numerical simulation of boundary-layer transition at Mach two

The linear and early nonlinear stages of boundary-layer transition at free-stream Mach numberM ==2.0 are investigated by direct numerical simulation of the compressible Navier-Stokes equations. Results from simulations with a large computational box and small-amplitude random initial conditions are compared with linear stability theory. The growth rates of oblique waves are reproduced correctly. Two-dimensional waves show a growth that is modulated in time, indicating the presence of an extra unstable mode which moves supersonically relative to the free stream. Further simulations are conducted to investigate the nonlinear development of two- and three-dimensional disturbances The transition due to oblique disturbance waves is the most likely cause of transition at this Mach number, and is found to lead to the development of strong streamwise vortices.     

Phase structure change and ER effect in liquid crystalline polymer/dimethylsiloxane blends

The mechanism of the electrorheological (ER) effect in two types of liquid crystalline polymer (LCP)/dimethylsiloxane (DMS) blends was investigated by rheological measurements and by structure observation under electric field and shear flow. The results show that the phase structures of these immiscible blends can be categorized into slipping (low viscosity) and non-slipping (high viscosity) states. In the non-slipping state, higher viscosity LCP domains connect the electrodes. In the slipping state, on the other hand, LCP domains do not connect the electrodes and the shear is mainly confined in the lower viscosity DMS domains. The ER effect (electrically induced viscosity increase) originates from the electrically induced slipping to non-slipping transition. In one of the blends, the ER effect occurs only at high shear rate, since this blend is in non-slipping state even under no field if the shear rate is low. Received: 29 April 1997 Accepted: 3 November 1997